Properties | More Info | Isotopes | Spectra
Compounds | Reactions | Production
Atomic: M.A.C. | Reference
Images | Video
Reactions of Ruthenium
Reactions with water
Ruthenium does not react with water under normal conditions.
Reactions with air
Ruthenium is largely immune to atmospheric attack. On heating with oxygen, ruthenium metal gives ruthenium (IV) oxide.
  Ru(s) + O2(g)RuO2(s)
Reactions with halogens
Ruthenium reacts with excess of fluorine to form ruthenium(VI) fluoride.
  Ru(s) + 3F2(g)RuF6(s)
Heating ruthenium metal at 330°C with chlorine in the presence of carbon monoxide produces dark brown ruthenium(III) chloride, RuCl3; further heating of this product under Cl2 yields a black form of ruthenium(III) chloride.
Reduction Potentials
Balanced half-reaction E0 / V
Ru2+ + 2e-Ru(s) +0.45
RuO2(s) + 4H+ + 4e-Ru(s) + 2H2O +0.79
RuO4(s) + e-RuO4- +1.00
RuO4- + e-RuO42- +0.59
RuCl5- + 2e-Ru2+ + 5Cl- +0.3
RuCl3 + 3e-Ru(s) + 3Cl- +0.68