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Atomic: M.A.C. | Reference
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Reactions of Niobium
Reactions with water
Niobium does not react with air under normal conditions as surface is protected by a thin oxide layer.
Reactions with air
Niobium does not react with air under normal conditions as surface is protected by a thin oxide layer.
Reactions with halogens
Niobium does react with the halogens upon warming to form niobium(V) halides.
  2Nb(s) + 5F2(g)NbF5(s)
  2Nb(s) + 5Cl2(g)NbCl5(s)
  2Nb(s) + 5Br2(g)NbBr5(s)
  2Nb(s) + 5I2(g)NbI5(s)
Reactions with acids
Niobium appears not to be attacked by many acids at room temperature but does dissolve in hydrofluoric acid, HF, or in a mixture of HF and nitric acid, HNO3.
Reactions with bases
Niobium metal is largely resistant to attack by molten alkali but will dissolve slowly.
Reduction Potentials
Balanced half-reaction E0 / V
NbV + 2e-NbIII -0.373
Nb3+ + 3e-Nb(s) -1.1
Nb2O5(s) + 10H+ + 10e-2Nb(s) + 5H2O -0.65
NbO3+ + 2H+ + 2e-Nb3+ + H2O -0.343
NbO(SO4)2- + 2H+ + 2e-Nb3+ + H2O + 2SO42- -0.1
NbO(SO4)2- + 2H+ + 5e-Nb(s) + H2O + 2SO42- -0.63