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Atomic: M.A.C. | Reference
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Reactions of Zirconium
Reactions with water
Zirconium does not react with water under normal conditions.
Reactions with air
Zirconium is coated with an oxide layer that usually renders it inactive. However zirconium does burn in air if provoked to form zirconium(IV) oxide, ZrO2.
  Zr(s) + O2(g)ZrO2(s)
Reactions with halogens
Zirconium does react with the halogens, upon warming, to form zirconium(IV) halides.
  Zr(s) + 2F2(g)ZrF4(s)
  Zr(s) + 2Cl2(g)ZrCl4(s)
  Zr(s) + 2Br2(g)ZrBr4(s)
  Zr(s) + 2I2(g)ZrI4(s)
Reactions with acids
Zirconium metal is coated with an oxide layer that usually renders it inactive. Most cold mineral acids have little effect. Zirconium does dissolve in hydrofluoric acid, HF, presumably to form fluoro complexes.
Reactions with bases
Zirconium does not appear to react wih alkalis under normal conditions, even when hot.
Reduction Potentials
Balanced half-reaction E0 / V
Zr4+ + 4e-Zr(s) -1.539
H2ZrO3(s) + H2O + 4e-Zr(s) + 4OH- -2.36
HZrO3- + 5H+ + 4e-Zr(s) + 3H2O -1.276
ZrO2+ + 2H+ + 4e-Zr(s) + H2O -1.570
ZrO2(s) + 4H+ + 4e-Zr(s) + 2H2O -1.456
ZrO2.H2O(s) + 4H+ + 4e-Zr(s) + 3H2O3 -1.53
ZrO2.2H2O + 4H+ + 4e-Zr(s) + 4H2O -1.553